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1

Diarylphosphinic azides: Photochemical reactions including rearrangement in methanol

Martin J.P. Harger, Sally Westlake

Journal:

Year:

1982

Language:

english

File:

PDF, 693 KB

english, 1982

2

O-(diphenylphosphinyl)hydroxylamine

Harger, Martin J. P.

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1979

Language:

english

File:

PDF, 135 KB

english, 1979

3

SPIE Proceedings [SPIE 1989 Orlando Symposium - Orlando, FL (Monday 27 March 1989)] Millimeter Wave and Synthetic Aperture Radar - Synthetic Aperture Radar: A Kelvin Wake Image Artifact

Harger, Robert O., Huddleston, G. K., Tanenhaus, Martin E., Williams, Brian P.

Year:

1989

Language:

english

File:

PDF, 14.12 MB

english, 1989

4

Reexamination of the Evidence for Solvent-Induced Intramolecular Electrophilic Catalysis by a cis Vicinal Hydroxyl Group in Ribonucleoside Phosphorylation Reactions

Paul M. Cullis, Martin J. P. Harger, Michael Lee

Journal:

Angewandte Chemie

Year:

2000

Language:

english

File:

PDF, 70 KB

english, 2000

5

Reexamination of the Evidence for Solvent-Induced Intramolecular Electrophilic Catalysis by a cis Vicinal Hydroxyl Group in Ribonucleoside Phosphorylation Reactions

Paul M. Cullis, Martin J. P. Harger, Michael Lee

Journal:

Angewandte Chemie International Edition

Year:

2000

Language:

english

File:

PDF, 70 KB

english, 2000

6

ChemInform Abstract: Nucleophilic Substitution Reactions of Benzyl- and Diphenylmethylphosphonamidic Chlorides with Amines: Competition Between the Usual SN2(P) Mechanism and Elimination—Addition with an Alkylideneoxophosphorane (Phosphene) Intermediate.

Martin J. P. Harger

Journal:

Year:

2001

Language:

english

File:

PDF, 33 KB

english, 2001

7

ChemInform Abstract: Phosphorochloridates from Phosphorohydrazides with ButOCl: Stereospecificity, Selectivity and Phosphorylium Ion Intermediates.

Martin J. P. Harger

Journal:

Year:

2001

File:

PDF, 34 KB

2001

8

ChemInform Abstract: Reactive Species Formed from N-Benzyloxycarbonyl α-Aminophosphonochloridates and Triethylamine: Probable Identity and Implications for Synthesis.

Paul M. Cullis, Martin J. P. Harger

Journal:

Year:

2002

File:

PDF, 31 KB

2002

9

Photolysis of some unsymmetrical phosphinic azides in methanol: Relative migratory aptitudes of alkyl groups and phenyl in the curtius-like rearrangement

Martin J.P. Harger, Sally Westlake

Journal:

Year:

1982

Language:

english

File:

PDF, 470 KB

english, 1982

10

Nucleophilic substitution in benzylic phosphonothioic dichlorides formation of a diamide without intervention of the amidic chloride

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1996

Language:

english

File:

PDF, 119 KB

english, 1996

11

N-(dialkylphosphinoyl)hydroxylamines : Preparation using N,O-bis(trimethylsilyl)hydroxylamine and migration of simple alkyl groups in the rearrangements of their O-p-nitrobenzenesulphonates

Martin J.P. Harger, P.Andrew Shimmin

Journal:

Year:

1992

Language:

english

File:

PDF, 847 KB

english, 1992

12

N-(Diphenylphosphinothioyl)hydroxylamine Transposition of O and S in its O-benzoyl derivative

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1993

Language:

english

File:

PDF, 125 KB

english, 1993

13

Substituent effects in the acid-catalysed hydrolysis of alkylphenylphosphinanilides

Martin J.P. Harger, Andrew J. Macpherson, David Pickering

Journal:

Tetrahedron Letters

Year:

1975

Language:

english

File:

PDF, 128 KB

english, 1975

14

Steric inhibition of the acid-catalysed hydrolysis of diphenylphosphinic amides

Anne C. Clements, Martin J.P. Harger, Alan Leonard, Michael D. Reed

Journal:

Tetrahedron Letters

Year:

1976

Language:

english

File:

PDF, 129 KB

english, 1976

15

Methoxide-induced rearrangement of some N-t-butyl α-chlorophosphonamidates evidence for azaphosphiridine oxide intermediates

Martin J.P Harger, Andrew Williams

Journal:

Tetrahedron Letters

Year:

1986

Language:

english

File:

PDF, 129 KB

english, 1986

16

Dimethylsulphide as a nitrene trap in the photolysis of some phosphinic azides

Martin J.P. Harger, Sally Westlake

Journal:

Tetrahedron Letters

Year:

1982

Language:

english

File:

PDF, 132 KB

english, 1982

17

Methoxide-catalysed rearrangement of N- to O-(diphenylphosphinyl)hydroxylamine

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1983

Language:

english

File:

PDF, 137 KB

english, 1983

18

N,O-bis(diphenylphosphinoyl)hydroxylamine base-induced rearrangement to a phosphonamidic-phosphinic mixed anhydride

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1990

Language:

english

File:

PDF, 242 KB

english, 1990

19

Preparation of simple N-(dialkylphosphinoyl)hydroxylamines and alkyl migration in the rearrangements of their O-p-nitrobenzenesulphonates

Martin J.P. Harger, P. Andrew Shimmin

Journal:

Tetrahedron Letters

Year:

1991

Language:

english

File:

PDF, 158 KB

english, 1991

20

Phosphorochloridates from phosphorohydrazides with ButOCl: stereospecificity, selectivity and phosphorylium ion intermediates

Martin J.P Harger

Journal:

Tetrahedron Letters

Year:

2001

Language:

english

File:

PDF, 106 KB

english, 2001

21

An elimination-addition mechanism for some phosphonamidic chloride-amine reactions

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1981

Language:

english

File:

PDF, 164 KB

english, 1981

22

Proton magnetic resonance spectra of chiral phosphorus esters: Chemical shift non-equivalence of enantiomers induced by optically active phosphinothioic acids

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1978

Language:

english

File:

PDF, 157 KB

english, 1978

23

Transposition of the phosphinoyl groups in the base-induced rearrangements of N,O-Bis(diarylphosphinoyl)hydroxylamines

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1997

Language:

english

File:

PDF, 109 KB

english, 1997

24

Rearrangement of O-benzoyl-N-(diphenylphosphinothioyl) hydroxylamine: An 18O-labelling investigation of oxygen-sulfur transposition

Martin J.P. Harger

Journal:

Tetrahedron Letters

Year:

1998

Language:

english

File:

PDF, 104 KB

english, 1998

25

Reactions of N-phenyl ?-halogenophosphonamidates with alkoxide: migration of the anilino group from phosphorus to the ? carbon atom

Harger, Martin J. P., Williams, Andrew

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1986

Language:

english

File:

PDF, 946 KB

english, 1986

26

P62 Preditor: An organized and efficient approach for ensuring data quality in a clinical trial

Jeffrey Martin, David Burry, Gerald Swanson, Kimberly Beringer, Sharon Crow, Regina Hardison, Gail Harger, Margaret Cooper, Andrea Siewers

Journal:

Controlled Clinical Trials

Year:

1993

Language:

english

File:

PDF, 73 KB

english, 1993

27

Rapid DNA sequencing based upon single molecule detection

Lloyd M. Davis, Frederic R. Fairfield, Carol A. Harger, James H. Jett, Richard A. Keller, Jong Hoon Hahn, Letitia A. Krakowski, Babetta L. Marrone, John C. Martin, Harvey L. Nutter, Robert L. Ratliff,

Journal:

Genetic Analysis: Biomolecular Engineering

Year:

1991

Language:

english

File:

PDF, 789 KB

english, 1991

28

Lossen-like rearrangement of N-[?-methylbenzyl(phenyl)phosphinoyl]-O-methylsulfonylhydroxylamine with methylamine: retention of configuration at phosphorus as revealed by X-ray crystallography

Fawcett, John, Harger, Martin J. P., Menon, Ramesh Sreedharan

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1992

Language:

english

File:

PDF, 260 KB

english, 1992

29

The origin of the amide formed in the photochemical reactions of aminimides: rearrangement of trimethylammonio-N-diphenylphosphinoylimide to N-(dimethylaminomethyl)diphenylphosphinic amide

Martin, Sally Freeman, Harger, J. P.

Journal:

Journal of the Chemical Society Chemical Communications

Year:

1985

Language:

english

File:

PDF, 196 KB

english, 1985

30

Use of an 18O-labelled phosphonamidic-sulfonic anhydride to learn more about the mechanism by which O-sulfonyl-N-phosphinoylhydroxylamines rearrange

Harger, Martin J. P.

Journal:

Organic & Biomolecular Chemistry

Year:

2006

Language:

english

File:

PDF, 107 KB

english, 2006

31

Scrambling of the label in a fluorenylphosphonamidic [18O]-sulfonate during dissociative nucleophilic substitution (elimination?addition): a measure of the importance of preassociation

Harger, Martin J. P.

Journal:

Organic & Biomolecular Chemistry

Year:

2006

Language:

english

File:

PDF, 109 KB

english, 2006

32

N-(Diphenylphosphinothioyl)hydroxylamine: preparation, characterisation and base-induced transposition of sulfur and oxygen atoms in its O-benzoyl derivative 1

Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1997

Language:

english

File:

PDF, 104 KB

english, 1997

33

N-(alkylphenylphosphinoyl)hydroxylamines: highly selective migration of the phenyl group in the base-induced rearrangement of their O-methylsulphonyl derivatives

Harger, Martin J. P., Smith, Adrian

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1987

Language:

english

File:

PDF, 769 KB

english, 1987

34

Base-induced rearrangement of tetraalkyl(diphenylphosphinoyl)hydrazinium salts to phosphinoyl aminals; possible relevance to the photochemical rearrangement of trialkylammonio(diphenylphosphinoyl)imides

Freeman, Sally, Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1990

Language:

english

File:

PDF, 683 KB

english, 1990

35

Rearrangement reactions of N-phosphinoyl-O-sulfonylhydroxylamines with amines: detection of a phosphonamidic?sulfonic mixed anhydride intermediate by nuclear magnetic resonance spectroscopy

Harger, Martin J. P., Sreedharan-Menon, Ramesh

Journal:

Chemical Communications

Year:

1996

Language:

english

File:

PDF, 248 KB

english, 1996

36

Influence of ortho methyl and isopropyl substituents on the reactivity of N-t-butyl P-arylphosphonamidic chlorides with isopropylamine and t-butylamine: steric acceleration of metaphosphonimidate formation by an elimination addition mechanism; contrasting behaviour of N,N-dimethyl P-arylphosphonamidic chlorides

Freeman, Sally, Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1987

Language:

english

File:

PDF, 1.16 MB

english, 1987

37

N-chloro- and NN-dichloro-derivatives of some phosphinic amides preparation and reactions with anthracene, anisole, and triphenylarsine

Harger, Martin J. P., Stephen, Michael A.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1980

Language:

english

File:

PDF, 1.03 MB

english, 1980

38

Photochemical rearrangement of dialkylphosphinic azides in methanol and other protic solvents

Harger, Martin J. P., Stephen, Michael A.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1981

Language:

english

File:

PDF, 765 KB

english, 1981

39

Preparation and characterisation of N-(diphenylphosphinoyl)hydroxylamine, and conversion into O-sulphonyl derivatives that undergo Lossen-like rearrangement

Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1983

Language:

english

File:

PDF, 920 KB

english, 1983

40

Mechanism and Stereochemistry of Diphosphate Formation from Dioxaphosphorinanes: A Critical Reassessment

Cullis, Paul M., Fawcett, John, Griffith, Gerald A., Harger, Martin J. P., Lee, Michael

Journal:

Journal of the American Chemical Society

Year:

2001

Language:

english

File:

PDF, 121 KB

english, 2001

41

A new mechanism for nucleophilic substitution at a thiophosphoryl centre revealed by the reaction of diisopropylamine with PSCl3

Harger, Martin J. P.

Journal:

Chemical Communications

Year:

2005

Language:

english

File:

PDF, 293 KB

english, 2005

42

Photochemical reactions of trialkylammonio-N-diphenylphosphinoylimides: rearrangement to N-phosphinoyl aminals and the formation of diphenylphosphinic amide

Freeman, Sally, Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1989

Language:

english

File:

PDF, 1.04 MB

english, 1989

43

Phosphoramidic acid monoesters as phosphorylating agents: steric effects and reluctance to form monomeric metaphosphate intermediates

Harger, Martin J. P.

Journal:

Chemical Communications

Year:

2004

Language:

english

File:

PDF, 125 KB

english, 2004

44

Phosphonamidothioic acids as thiophosphonylating agents: stereochemistry of reactions of N-tert-butyl-P-phenylphosphonamidothioic acid with alcohols

Harger, Martin J. P., Pater, Christopher

Journal:

Chemical Communications

Year:

1999

Language:

english

File:

PDF, 127 KB

english, 1999

45

Hydrolysis of diarylphosphinic amides in acidic solution: steric inhibition and mechanism

Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

1980

Language:

english

File:

PDF, 1.09 MB

english, 1980

46

Stereochemical evidence for elimination–addition and a methylenethioxophosphorane (thiophosphene) intermediate in nucleophilic substitution at the PS centre of a benzylic phosphonamidothioic chloride

Harger, Martin J. P.

Journal:

Chemical Communications

Year:

1998

Language:

english

File:

PDF, 47 KB

english, 1998

47

Migration of a benzyl group in the Lossen-like rearrangement of an N-phosphinoyl-O-sulphonylhydoxylamine

Harger, Martin J. P., Smith, Adrian

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1990

Language:

english

File:

PDF, 749 KB

english, 1990

48

Rearrangement reactions of N-phosphinoyl-O-sulphonylhydroxylamines with amines under competitive conditions. Possible involvement of monomeric metaphosphonimidates and phosphonamidic sulphonic mixed anhydrides

Harger, Martin J. P., Smith, Adrian

Journal:

Journal of the Chemical Society Perkin Transactions 1

Year:

1990

Language:

english

File:

PDF, 750 KB

english, 1990

49

Nucleophilic substitution in benzylic thiophosphinyl and thiophosphonyl chlorides: the contribution of elimination?addition pathways with methylenethioxophosphorane (thiophosphene) intermediates

Coogan, Michael P., Harger, Martin J. P.

Journal:

Journal of the Chemical Society Perkin Transactions 2

Year:

1994

Language:

english

File:

PDF, 1010 KB

english, 1994

50

Base induced rearrangement of N,O-bis(diphenylphosphinoyl)hydroxylamine: 18O-labelling evidence on how the phosphonamidic-phosphinic anhydride product is formed

Harger, Martin J. P.

Journal:

Chemical Communications

Year:

1997

Language:

english

File:

PDF, 98 KB

english, 1997

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